You'll get hooked if you do, Fluxy. It's sooooo nice to be able to just walk away from a completely soaked car, knowing that's it's gonna dry with no spots. Very cool.
Yeah, you'll want to bypass the water softener, for sure. You CRSpotless will still *work* if you throw softened water through it, but you'll wear out one of the resin types (I believe it's the anion resin that would be worn out, but I'd have to go back and do some reading to be 100% positive) while your other resin just kinda did nothing.
I've been meaning to go back and look into this further.. I think that for those guys that have softened water to their garden hose spigot, you could get by with using only one type of DI resin to finish the job. That job being to get rid of the remaining minerals the water softener didn't. I'm just not completely sure which resin it is. I'm *fairly* sure that it's the anion resin that's needed. Although the water wouldn't really be "balanced" if you did it this way.... Guess I better attempt to explain "balanced"....
Let's assume one filter full of cation resin, and one filled with anion....
When water goes through the cation filter (the first filter to receive water), certain mineral ions are replaced by hydrogen. So the water comes out with extra hydrogen in it (it's slightly acidic). Then the water hits the anion resin next. The anion exchanges certain minerals for oxygen. The free hydrogen from the cation resin and the free oxygen from the anion resin party it up to become water.
The cation (acid) resin can be made to exchange *either* (but not both) sodium or hydrogen. In a water softener, it exchanges sodium into the water. So now if you run water that has sodium in it through the anion, it's not gonna have the hydrogen in it (it has sodium instead) to pair up with the oxygen it releases. This will leave your water "unbalanced"; it'll be slightly basic, and loaded with sodium.
If your water is really hard, it'll be loaded with sodium to the point that you'll get white sodium spots on your car when it dries (been there, done that).