NESLAB, cooling systems manufacture, writes in the Instruction and Operation Manual: "Higly distilled/deionized water, above the 3 megohm-cm region, may become aggressive and is not recommended for use with units with wetted parts other than stainless steel. Distiled/deionized water in the 15 megohm-cm region is definitely aggressive and should not be used."
This is not the correct reference for what we are talking about here. The usage of ultrapure water in cooling systems is very different from washing your car with some DI water.
Extremely pure water (much more pure than an OTC DI product will get you) will dissolve a minute amount of what it contacts--but even tiny trace amounts of silica (very hard to remove from water, BTW) inhibit corrosion.
Also, this needs to be a high velocity environment, where the water is continually dissolving and taking away ions--in a static environment, the ions would saturate the droplet, and no further dissolution would occur.
BTW, the same happens with your ordinary droplet of "polluted" water, too.
Standard corrosion occurs when there is a salt/solid in the water, because corrosion is an electrochemical reaction. My best friend (a chemical engineer for steel manufacturer) tells me that steel makers test corrosive resistance of steel samples by placing them within 100 yards of an ocean coast. The salt spray is what corrodes the steel.