A Random Orbit/dual action polisher like the Porter Cable moves in a off center motion. It feels like its vibrating but its actually moving in a tight figure 8 motion. This motion means it generates less heat so you don't have to worry about burning or removing the paint from a car.
A rotary buffer on the other hand is a much more pwoerful machine. The buffer head/pad moves in a clockwise manner with no random orbit or figure it motion. Its liek attaching a foam pad onto a drill. the will generate a lot of heat and without proper technique or patience you will burn the paint, remove the paint, creat new swirl marks, or possibly pop off a piece of molding or trim.
The PC is a good polisher it will make all but the worst finishes better. The rotary polisher in the hands of a experienced user will make the most neglected finishes look new again, but some cars just need a new paint job.
If you have a newer car, or a well taken care of car, the PC will make everything move along faster and with better results.
Jason