Sean..here you go...now let's see your proof!!!!!!
Poorboy's World
17 Brookhill Dr.
W. Nyack, NY 10994
MATERIAL SAFETY DATA SHEET (MSDS)
Spray and Rinse
Section I
MSDS PREPARATION DATE: July 1, 2005
TELEPHONE NUMBER FOR INFORMATION: 845-627-5907
Section II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION
Specific Chemical Identity OSHA PEL ACGIH TLV
Ammonium Hydrogen Difluoride (CAS# 1341-49-7) TWA 2.5 MG(F)/M3 2.5 MG(F)/M3
TWA 2.5 MG(F)/M3
Section III - PHYSICAL AND CHEMICAL CHARACTERISTICS
BOILING POINT: 220 F
SPECIFIC GRAVITY (WATER=1): >1
VAPOR PRESSURE (MM HG.): N/D
MELTING POINT: N/A
VAPOR DENSITY (Air=1): N/D
EVAPORATION RATE, n-Bu Acetate=1: <1
APPEARANCE AND ODOR: Hazy liquid with citrus odor
SOLUBILITY IN WATER: Complete
Section IV - FIRE FIGHTING MEASURES
FLASH POINT: Material does not exhibit a flash point.
FLAMMABLE LIMITS LEL: NA UEL: NA
EXTINGUISHING MEDIA: Use water, carbon dioxide or foam.
SPECIAL FIRE FIGHTING METHOD: Wear positive pressure self-contained breathing apparatus.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Toxic emissions are possible in a fire situation. Not a fire or
explosion hazard.
Section V - REACTIVITY DATA
STABILITY: Stable.
CONDITIONS TO AVOID: None known.
INCOMPATIBILITY (MATERIALS TO AVOID): Strong acids.
HAZARDOUS DECOMPOSITIONS OR BYPRODUCTS: NH3 NO. If contacted with strong acids, HF will be
released. With strong alkali, NH3 will be released.
HAZARDOUS POLYMERIZATION: Will Not Occur.
CONDITIONS TO AVOID: None known.
Section VI - HEALTH HAZARD DATA
ROUTES OF ENTRY: Inhalation, skin, and ingestion
HEALTH HAZARDS ACUTE: Skin absorption, apparent dermal LD50>2gms/kg body weight.
Ingestion, apparent acute dermal LD50 is 406 mg/kg body weight.
CHRONIC: Repeated exposure to excessive concentrations of fluorides over years
may lead to embrittlement and decalcification of bones do to fluoride deposition.
CARCINOGENICITY:
NTP? Not Listed IARC MONOGRAPHS? Not Listed OSHA REGULATED? Not Listed
Poor Boy’s World
MSDS- Spray and Rinse
Page 1
SIGNS AND SYMPTOMS OF EXPOSURE:
Eye contact: moderately irritation on Draize test. May cause burn.
Inhalation: causes severe irritation
Skin Contact: Ammonium Bifluoride may cause severe chemical burns, which may not be
immediately apparent.
Ingestion: may cause severe burns to the gastrointestinal tract. Absorption of fluoride may cause
death.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: May aggravate preexisting skin or
respiratory ailments.
EMERGENCY AND FIRST AID PROCEDURES:
EYE: Immediately flush with plenty of water or normal saline for at least 15 minutes. Obtain
immediate medical attention.
SKIN: Immediately rinse exposed area with water for several minutes. Remove contaminated
clothing. If immediate rinsing is not performed seek medical attention.
INHALATION: Remove to fresh air. For severe or prolonged high level exposure, seek medical
attention.
INGESTION: Do not induce vomiting. Immediately administer by mouth any available substance
that contains calcium (Tums, milk) or magnesium (Maalox, Mylanta.) DO NOT administer activated charcoal.
Obtain immediate medical attention.
Section VII - PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Contain spill. Remove with inert
absorbent material. Wash spill area with water.
WASTED DISPOSAL METHOD: In accordance with Federal, State and local regulations.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Wash thoroughly after handling. Keep
containers closed when not in use. Store away from food and food products.
OTHER PRECAUTIONS: Store away from strong alkalis. Avoid contact with skin or any body parts or
clothing that could absorb product. Keep out of the reach of children. Do not get in eyes or on skin.
Section VIII - CONTROL MEASURES
RESPIRATORY PROTECTION: None required if adequate ventilation is maintained. Otherwise, a
NIOSH/MSHA approved organic vapor full face respirator is advised.
VENTILATION: Local exhaust.
OTHER PROTECTIVE CLOTHING: Eye wash and safety shower should be available.
WORK HYGIENIC PRACTICES: Do not get in eyes, on skin or on clothing. Use only with adequate
ventilation. Observe good housekeeping practices.
EYE PROTECTION: Approved safety glasses with side shields.
PROTECTIVE GLOVES: Rubber or neoprene.
Section XVI - OTHER INFORMATION
HAZARD RATING SYSTEMS: This information is for people trained in National Fire Protection Association
(NFPA 704) Identification of the Fire Hazards of Materials.
NFPA 704 KEY: NFPA
HEALTH 3 4=Extreme
FLAMMABILITY 0 3=High
REACTIVITY 2 2=Moderate
1=Slight
0=Insignificant
May be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910,1200. Standard
must be consulted for specific requirements.
Poor Boy’s World
MSDS- Spray and Rinse
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